[(Fe(η5-C5H4PPh2)2)[AuSC(=NPh)N(CH2CH2)O]2] | 876289-27-9

• 英文名称: [(Fe(η5-C5H4PPh2)2)[AuSC(=NPh)N(CH2CH2)O]2]
• 英文别名: dppf[AuSC(=NPh)N(CH2CH2)2O]2
• CAS: 876289-27-9
• 化学式: C₅₆H₅₄Au₂FeN₄O₂P₂S₂
• 分子量: 1390.93
• InChiKey: XDSOTYOZFZPGNA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-phenyl-1-morpholinethiocarbamide 、 (1,1'-双(二苯基膦)二茂铁)二氯化二金 在 trimethylamine 作用下， 以 甲醇 、 水 为溶剂， 以81%的产率得到[(Fe(η5-C5H4PPh2)2)[AuSC(=NPh)N(CH2CH2)O]2]
  参考文献：
  名称：

  Synthesis, characterisation, supramolecular aggregation and biological activity of phosphine gold(I) complexes with monoanionic thiourea ligands

  摘要：

  A series of phosphine gold(I) complexes containing monoanionic thiourea ligands has been synthesised by reaction of the appropriate precursor chloro complex, Ph3PAuCl, Cy3PAuCl, dppf(AuCl)(2) [dppf = Fe(eta(5)-C5H4PPh2)(2)] or dppe(AuCI)2 (dppe = Ph2PCH2CH2PPh2) with the thiourea and Me3N base in methanol solution. The complexes have been fully characterised by elemental analysis, NMR spectrometry, electrospray mass spectrometry, and in several cases, by single-crystal X-ray diffraction studies. The crystallographic studies show that the ligands coordinate as a thiolate in each case with systematic variations in geometric parameters being readily ascribed to the influence of the N-bound substituents. In four of the structures, discernable supramolecular aggregation patterns are evident, leading to loosely associated dimers or chain motifs, the latter mediated by either An...S, N-H...N or C-H...O interactions. Cytotoxicity data, against the P388 leukemia cell line, and anti-microbial data are also reported. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.07.046