[1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethane]trizinc-bis(μ-triisopropylsilylphosphanediide) | 355134-15-5

• 英文名称: [1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethane]trizinc-bis(μ-triisopropylsilylphosphanediide)
• CAS: 355134-15-5
• 化学式: C₄₂H₈₂N₄P₂Si₄Zn₃
• 分子量: 1013.6
• InChiKey: OQDORMBHWPDYRA-SXGJPOQHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethane]trizinc-bis(μ-triisopropylsilylphosphanediide) 、 苯 以 苯 为溶剂， 生成 [1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethane]trizinc-bis(μ-triisopropylsilylphosphanediide)*C6H6
  参考文献：
  名称：

  Reaktion von Bis(methylzink)-1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethan mit Triisopropylsilylphosphan und -arsan

  摘要：

  The reaction of bis(methylzinc)-1,2-dipyridyl-1,2bis(tert-butyldimethylsilylamido)ethane (1) with triisopropylsilylphosphane gives the three-nuclear complex [1,2-dipyridyl-1,2-bis(tert-butyldimethylsilyl amido)e thane] trizinc-bis(mu -triisopropylsilylphosphanediide) (2). Two zinc atoms show the coordination number of four whereas the third metal center is located between the two phosphorus atoms with a bent P-Zn-P-moiety. The reaction of 1 with triisopropylsilylarsane proceeds analoguesly, however, we were not able to isolate analytically pure [1,2-dipyridyl-1,2-bis (tert-butyldimethylsilylamido) ethane] trizinc-bis (mu -triisopropylsilylarsanediide) (3).

  DOI：

  10.1002/1521-3749(200106)627:6<1141::aid-zaac1141>3.0.co;2-a
• 作为产物：
  描述：

  bis(methylzinc) 1,2-dipyridyl-1,2-bis((tert-butyldimethylsilyl)amido)ethane 、 Tri-isopropylsilylphosphan 以 甲苯 为溶剂， 以68%的产率得到[1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethane]trizinc-bis(μ-triisopropylsilylphosphanediide)
  参考文献：
  名称：

  Reaktion von Bis(methylzink)-1,2-dipyridyl-1,2-bis(tert-butyldimethylsilylamido)ethan mit Triisopropylsilylphosphan und -arsan

  摘要：

  The reaction of bis(methylzinc)-1,2-dipyridyl-1,2bis(tert-butyldimethylsilylamido)ethane (1) with triisopropylsilylphosphane gives the three-nuclear complex [1,2-dipyridyl-1,2-bis(tert-butyldimethylsilyl amido)e thane] trizinc-bis(mu -triisopropylsilylphosphanediide) (2). Two zinc atoms show the coordination number of four whereas the third metal center is located between the two phosphorus atoms with a bent P-Zn-P-moiety. The reaction of 1 with triisopropylsilylarsane proceeds analoguesly, however, we were not able to isolate analytically pure [1,2-dipyridyl-1,2-bis (tert-butyldimethylsilylamido) ethane] trizinc-bis (mu -triisopropylsilylarsanediide) (3).

  DOI：

  10.1002/1521-3749(200106)627:6<1141::aid-zaac1141>3.0.co;2-a