(4'-(4-methylthiophenyl)-2,2':6',6''-terpyridine)trichlororuthenium(III) | 1158078-59-1

• 英文名称: (4'-(4-methylthiophenyl)-2,2':6',6''-terpyridine)trichlororuthenium(III)
• CAS: 1158078-59-1
• 化学式: C₂₂H₁₇Cl₃N₃RuS
• 分子量: 562.892
• InChiKey: FYGWPYRNVFNIDL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 (4'-(4-methylthiophenyl)-2,2':6',6''-terpyridine)trichlororuthenium(III) 在 N-ethylmorpholine 作用下， 以 乙醇 为溶剂， 以17%的产率得到[Ru(4′-(thiomethyl)-2,2′:6′,2″-terpyridine)₂](PF₆)₂
  参考文献：
  名称：

  The first complex of 4′-(4-methylthiophenyl)-2,2′:6′,2″-terpyridine – A model for terpylated self-assembled monolayers

  摘要：

  The complex [Ru(2)(2)][PF6](2) where 2 is 4'-(4-methylthiophenyl)-2,2':6',2"-terpyridine is the first example of a coordination compound of this ligand, and provides structural information relevant to understanding the interaction of self-assembled monolayers of related ligands with metal ions. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.01.030
• 作为产物：
  描述：

  水合三氯化钌 、 4′-(4-methylmercaptophenyl)-2,2′:6′2″-terpyridine 以 乙醇 为溶剂， 以55%的产率得到(4'-(4-methylthiophenyl)-2,2':6',6''-terpyridine)trichlororuthenium(III)
  参考文献：
  名称：

  The first complex of 4′-(4-methylthiophenyl)-2,2′:6′,2″-terpyridine – A model for terpylated self-assembled monolayers

  摘要：

  The complex [Ru(2)(2)][PF6](2) where 2 is 4'-(4-methylthiophenyl)-2,2':6',2"-terpyridine is the first example of a coordination compound of this ligand, and provides structural information relevant to understanding the interaction of self-assembled monolayers of related ligands with metal ions. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.01.030

文献信息

• Synthesis, crystal structure and water oxidation activity of [Ru(terpy)(bipy)Cl]⁺ complexes: influence of ancillary ligands on O₂ generation
  作者：Rekha Dhiman、Namita Singh、Bharat Ugale、C. M. Nagaraja

  DOI：10.1039/c7ra07186h

  日期：——

  various spectroscopic techniques. The molecular structures of the complexes 1 and 2 were determined by single crystal X-ray diffraction analysis. Catalytic activity for chemical oxidation of water of the complexes 1–4 reveals that the rate of O2 evolution follows the trend 1 > 4 > 2 > 3. Except the unsubstituted complex 1, the catalytic rate for O2 generation of 2 and 4, containing electron-donating (–CH3)

  四个新的Ru（II）络合物，[Ru II（MeMPTP）（bpy）Cl] PF 6（1），[Ru II（MeMPTP）（dmbpy）Cl] PF 6（2），[Ru II（MeMPTP）（dmcbpy） ）Cl] PF 6（3）和[Ru II（MeMPTP）（Pic）2 Cl] PF 6（4）[其中，MeMPTP = 4'-（4-甲基巯基苯基）-2,2'：6'2'' -叔吡啶，bpy = 2,2'-联吡啶，dmbpy = 4,4'-二甲基-2,2'-联吡啶，dmcbpy = 4,4'-二甲氧基羰基-2,2'-联吡啶，pic = 4-甲基吡啶]通过合成和表征各种光谱技术。配合物1和2的分子结构通过单晶X射线衍射分析确定。配合物1-4的水化学氧化催化活性表明O 2的释放速率遵循1 > 4 > 2 > 3的趋势。除了未取代的复杂1，用于O-催化速率2代的2和4，含有供电子性（-CH 3）基团，比的