[Pt(CH(COOMe)(CN))2(SePh)(Cl)(4,4'-(tert-butyl)2-2,2'-bipyridine)] | 676642-46-9

• 英文名称: [Pt(CH(COOMe)(CN))2(SePh)(Cl)(4,4'-(tert-butyl)2-2,2'-bipyridine)]
• CAS: 676642-46-9
• 化学式: C₃₂H₃₇ClN₄O₄PtSe
• 分子量: 851.163
• InChiKey: YPVGKSRKGDNDMC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(CH(COOMe)(CN))2(SePh)(Cl)(4,4'-(tert-butyl)2-2,2'-bipyridine)] 以 甲苯 为溶剂， 以70%的产率得到[Pt(CH(COOMe)CN)(Cl)(4,4'-(tert-butyl)2-2,2'-bipyridine)]
  参考文献：
  名称：

  Oxidative addition of Se–X bonds and reductive elimination of Se–C bonds in platinum compounds containing hydrocarbyl ligands

  摘要：

  The oxidative addition of PhSe-X molecules (X = Cl or Br) to Pt(II) complexes of formula [PtR(R')(N,N-chelate)] [R, R'= Me, CH(CO2Me)(2), CH(CO2Me)(CN); N,N-chelate=4,4'-(tert-butyl)(2)-2,2'-bipyridine] is described. The reaction quantitatively affords octahedral products [PtR(R')(SePh)(X)(N,N-chelate)], and is highly selective, since only the isomers with -X and -SePh in trans position are obtained. When R = R' = CH(CO2Me)(2) or R = R'= CH(CO2Me)(CN) an irreversible reductive elimination takes place in solution, giving rise to Pt(II) compounds [PtR(X)(N,N-chelate)] and organoselenium molecules PhSeR'. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00251-x
• 作为产物：
  描述：

  苯基氯化硒 、 [Pt(CH(COOMe)CN)2(4,4'-(tert-butyl)2-2,2'-bipyridine)] 以 二氯甲烷 为溶剂， 以70%的产率得到[Pt(CH(COOMe)(CN))2(SePh)(Cl)(4,4'-(tert-butyl)2-2,2'-bipyridine)]
  参考文献：
  名称：

  Oxidative addition of Se–X bonds and reductive elimination of Se–C bonds in platinum compounds containing hydrocarbyl ligands

  摘要：

  The oxidative addition of PhSe-X molecules (X = Cl or Br) to Pt(II) complexes of formula [PtR(R')(N,N-chelate)] [R, R'= Me, CH(CO2Me)(2), CH(CO2Me)(CN); N,N-chelate=4,4'-(tert-butyl)(2)-2,2'-bipyridine] is described. The reaction quantitatively affords octahedral products [PtR(R')(SePh)(X)(N,N-chelate)], and is highly selective, since only the isomers with -X and -SePh in trans position are obtained. When R = R' = CH(CO2Me)(2) or R = R'= CH(CO2Me)(CN) an irreversible reductive elimination takes place in solution, giving rise to Pt(II) compounds [PtR(X)(N,N-chelate)] and organoselenium molecules PhSeR'. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00251-x