| 1011489-79-4

• CAS: 1011489-79-4
• 化学式: C₅₃H₃₆ClOP₂Rh
• 分子量: 889.174
• InChiKey: RIDMVOBJZXTKQO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 碘甲烷 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Wide-Bite-Angle Diphosphinines: Design, Synthesis, and Coordination Properties

  摘要：

  A wide-bite-angle diphosphinine ligand has been designed and synthesized, which exhibits structural features for a preferred formation of trans complexes. Due to the linear orientation of the lone-pair electrons of the phosphorus donors in combination with an appropriate P-P distance, trans coordination toward a Rh center was observed and the corresponding LRh(CO)I complex could be characterized crystallographically. Although typical reactivities usually observed for trans complexes were found, reaction of the diphosphinine with the cis-enforcing precursor [Rh(nbd)(2)]BF(4) did result in the formation of several species at low temperature, to which cis-structures were attributed.

  DOI：

  10.1021/om7003546
• 作为产物：
  描述：

  2-[4-[2-[4-(4,6-Diphenylphosphinin-2-yl)phenyl]phenyl]phenyl]-4,6-diphenylphosphinine 、 di(rhodium)tetracarbonyl dichloride 以 二氯甲烷 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Wide-Bite-Angle Diphosphinines: Design, Synthesis, and Coordination Properties

  摘要：

  A wide-bite-angle diphosphinine ligand has been designed and synthesized, which exhibits structural features for a preferred formation of trans complexes. Due to the linear orientation of the lone-pair electrons of the phosphorus donors in combination with an appropriate P-P distance, trans coordination toward a Rh center was observed and the corresponding LRh(CO)I complex could be characterized crystallographically. Although typical reactivities usually observed for trans complexes were found, reaction of the diphosphinine with the cis-enforcing precursor [Rh(nbd)(2)]BF(4) did result in the formation of several species at low temperature, to which cis-structures were attributed.

  DOI：

  10.1021/om7003546