[(η5,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)RhCl2] | 913069-15-5

• 英文名称: [(η5,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)RhCl2]
• CAS: 913069-15-5
• 化学式: C₃₅H₁₆Cl₂F₁₉P₂Rh
• 分子量: 1033.24
• InChiKey: QJPHKYGFWBYDBE-YPQRFNQISA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium hexafluoroantimonate 、 [(η5,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)RhCl2] 以 not given 为溶剂， 以0%的产率得到[(η5,κP,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)RhCl][SbF6]
  参考文献：
  名称：

  Complexes of η5, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η5-pentamethylcyclopentadienyl in a rhodium complex

  摘要：

  The reaction between [{(eta(5)-C5Me5)RhCl(mu-Cl)}(2)] and (C6F5)(2)PCH2P(C6F5)(2) in refluxing benzene yields the singly linked complex [{(eta(5),kappa P-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)(2))}RhCl2] in which only one phosphorus atom is coordinated to the rhodium. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.01.019
• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 bis{bis(pentafluorophenyl)phosphino}methane 以 苯 为溶剂， 以70%的产率得到[(η5,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)RhCl2]
  参考文献：
  名称：

  Complexes of η5, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η5-pentamethylcyclopentadienyl in a rhodium complex

  摘要：

  The reaction between [{(eta(5)-C5Me5)RhCl(mu-Cl)}(2)] and (C6F5)(2)PCH2P(C6F5)(2) in refluxing benzene yields the singly linked complex [{(eta(5),kappa P-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)(2))}RhCl2] in which only one phosphorus atom is coordinated to the rhodium. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.01.019