[(CuF(BF4)(N,N,N',N'-tetramethylethane-1,2-diamine))2] | 352020-13-4

• 英文名称: [(CuF(BF4)(N,N,N',N'-tetramethylethane-1,2-diamine))2]
• CAS: 352020-13-4
• 化学式: C₁₂H₃₂B₂Cu₂F₁₀N₄
• 分子量: 571.111
• InChiKey: ATSPQRGUDOYCKG-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper(II) tetrafluroborate hexahydrate 、 四甲基乙二胺 在 triethyl orthoformate 作用下， 以 乙醇 为溶剂， 以50%的产率得到[(CuF(BF4)(N,N,N',N'-tetramethylethane-1,2-diamine))2]
  参考文献：
  名称：

  Copper(II) adducts with N,N,N′,N′-tetramethylethane-1,2-diamine and attempts to prepare trinuclear derivatives

  摘要：

  We have attempted to prepare complexes of the type [M3Cl5(tmen)(3)][BPh4] (tmen = Me2N(CH2)(2)NMe2) with M = Cu. Such species are already known for M = Ti, V, Fe, Ni, and Co, but we have been unable to prepare any Cu analogues. The [BPh4](-)appears to reduce Cu-II to Cu-I and we isolated the known [Cu(tmen)(2)][CuCl2] from reaction mixtures that contained it. Attempts to obviate this reduction by using a different anion were successful, but no triangulo species were isolated. However, during this work we isolated and structurally characterised [{CuF(BF4)(tmen)}(2)] and [{Cu(OH)(BF4)(tmen)}(2)]. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00378-4