[CuCl(N,N'-bis(pyridine-2-yl)phenylidene)-1,3-diaminopropan-2-ol)][ClO4]*MeOH | 1352144-11-6

• 英文名称: [CuCl(N,N'-bis(pyridine-2-yl)phenylidene)-1,3-diaminopropan-2-ol)][ClO4]*MeOH
• CAS: 1352144-11-6
• 化学式: CH₄O*C₂₇H₂₄ClCuN₄O*ClO₄
• 分子量: 651.006
• InChiKey: PPMZUVYDHWRDAJ-UERYJBODSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 copper(II) choride dihydrate 、 N,N’-bis((pyridine-2-yl)phenylidene)-1,3-diaminopropan-2-ol 、 sodium perchlorate 以 甲醇 为溶剂， 以72%的产率得到[CuCl(N,N'-bis(pyridine-2-yl)phenylidene)-1,3-diaminopropan-2-ol)][ClO4]*MeOH
  参考文献：
  名称：

  Copper(II) complexes with neutral Schiff bases: Syntheses, crystal structures and DNA interactions

  摘要：

  The synthesis and X-ray structural characterisation of a new Cu(II) complex, [Cu(L-1)Cl](ClO4)center dot CH3OH (1) [L-1 = N,N'-bis((pyridine-2-yl)phenylidene)-1,3-diaminopropan-2-ol], has been described in this work. The structural study reveals that the Cu(II) centre in 1 has a square pyramidal geometry with a trigonality index tau = 0.43, being coordinated by the organic ligand and a chloro group. The interaction of complex 1 and another complex previously reported by our group, [Cu(L-2)](ClO4)(2) (2) [L-2=N-(1-pyridin-2-yl-phenylidene)-N'-[2-({2-[(1-pyridin-2-ylphenylidene)amino]ethyl)amino)ethyl]ethane-1,2diamine], with calf thymus DNA (CT-DNA) has been investigated using absorption and emission spectral studies. The binding constant (K-b) and the linear Stern-Volmer quenching constant (K-sv) have been determined. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.10.037