1-ferrocenyl-N-(furan-2-ylmethyl) methanamine | 228099-77-2

• 英文名称: 1-ferrocenyl-N-(furan-2-ylmethyl) methanamine
• CAS: 228099-77-2
• 化学式: C₁₇H₁₈FeN₂
• 分子量: 306.19
• InChiKey: QCXFIQILMIKQDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 1-ferrocenyl-N-(furan-2-ylmethyl) methanamine 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, X-ray structural determination and Mössbauer characterization of Schiff bases bearing ferrocene groups, their reduced analogues and related complexes

  摘要：

  [1 + 1], [1 + 2], [2 + 1] or [3 + 1] acyclic and [1 + 1] or [2 + 2] cyclic Schiff bases (L-A... L-S), containing ferrocene moieties, have been prepared by reaction of formyl- or 1,1'-diformylferrocene and the appropriate amines. Formyl- and 1,1-diformylferrocene form respectively the acyclic [2 + 1] L-W and [2 + 2], L-Z compounds by reaction with 1,4-diaminomethylbenzene. Similar compounds (L-T... L-V,) have been obtained by condensation of aminomethylferrocene and 2,6-diformylpyridine, 2,6-diformyl-4-chlorophenol and 3-methoxy-2-hydroxybenzaldehyde. By reduction of these compounds with NaBH4 the corresponding ferrocene-amine derivatives (L') have been synthesized. All these compounds have been characterized by physico-chemical measurements (IR, NMR, Mossbauer spectroscopy and FAB mass spectrometry) and L-H, derived by the condensation of ferrocene-aldehyde and 1,5-diamino-3-oxa-pentane, also by an X-ray structural determination. The X-ray analysis of crystals of L-H, grown from a diethyl ether solution, shows that two independent molecules are present in the asymmetric unit; these two molecules are chemically equivalent with the ferrocenyl groups in the eclipsed form. The coordination ability of these compounds towards d metal ions as copper(II), nickel(II), platinum(II) and rhodium(III) was investigated; while the Schiff bases (L) may suffer hydrolysis, their reduced analogues (L') form stable, well-defined complexes of the type M(L')(Cl)(n) (n = 2, 3). The Mossbauer spectra of the prepared compounds show signals with delta at 0.44 and Delta E-Q 2.30 mm s(-1) for the Schiff bases L-A... L-S and 0.52 and 2.40 mm s(-1) for the reduced analogues and hence may be diagnostic of the presence of Fe-CH=N- or Fe-CH2-NH- groups. The signals with delta at 0.51-0.55 and Delta E-Q at 2.34-2.38 mm s(-1) for the Schiff bases L-T... L-V, having Fe-CH2-N=CH groups, resemble those of the reduced analogues. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00413-7
• 作为产物：
  描述：

  2-氨甲基吡啶 、 二茂铁甲醛 在 sodium tetrahydroborate 作用下， 以 甲苯 、 甲醇 为溶剂， 反应 6.0h， 生成 1-ferrocenyl-N-(furan-2-ylmethyl) methanamine
  参考文献：
  名称：

  染料敏化的TiO 2太阳能电池中 带有二茂铁基Ni（ii）和Cu（ii）二硫代氨基甲酸盐的二茂铁基的光敏活性†

  摘要：

  带有二茂铁的平面金属二硫代氨基甲酸酯，即[M（FcCH 2 dtc）2 ]（dtc =呋喃-2-基甲基二硫代氨基甲酸酯，M = Cu（II）1，Ni（II）4； dtc =苯并[ d ] [1,3 ] dioxol-5-基甲基二硫代氨基甲酸酯，M = Cu（II）2，Ni（II）5 ; dtc =吡啶-2-基甲基二硫代氨基甲酸酯，M = Cu（II）3，Ni（II）6 ; Fc =二茂铁基; Fe（ η 5 -C 5 H ^ 5）（η 5 -C 5 H ^4 –）），已通过显微分析，磁化率和循环伏安法进行了合成和表征。的结构1， 2和4已经通过单晶X射线衍射获得。这些在二硫代氨基甲酸酯配体中具有吡啶基，哌啶基和糠基作为杂芳族基团的配合物已被用作染料敏化的TiO 2太阳能电池中的敏化剂，用于将阳光转化为电能。使用这些敏化剂实现的光电能量转换效率大大高于使用我们先前报道的类似化合物获得的光电转换效率。总转换效率（

  DOI：

  10.1039/c3dt52142g