(N-methyl-bis(2-bromo 6-pyridylmethyl)amine)Fe(II)Cl2 | 845621-71-8

• 英文名称: (N-methyl-bis(2-bromo 6-pyridylmethyl)amine)Fe(II)Cl2
• CAS: 845621-71-8
• 化学式: C₁₃H₁₃Br₂Cl₂FeN₃
• 分子量: 497.827
• InChiKey: RIDAYHIVPBAHKT-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N-methyl-bis(2-bromo 6-pyridylmethyl)amine 、 iron(II) chloride 以 further solvent(s) 为溶剂， 以99%的产率得到(N-methyl-bis(2-bromo 6-pyridylmethyl)amine)Fe(II)Cl2
  参考文献：
  名称：

  N-methyl-bis(2-bromo 6-pyridylmethyl)amine: high yield synthesis, and spectroscopic properties of the dichloroferrous complex with trigonal bipyramidal geometry

  摘要：

  The new tridentate title ligand has been synthesized by a very convenient and high yield method. The dichloroferrous derivative was prepared in order to provide spectroscopic bases for solution studies of trigonal bipyramidal derivatives with aminomethylpyridyl containing ligands. Its crystal structure is reported, together with UV-Vis, H-1 NMR and molecular conductivity data. The absence of any MLCT in UV-Vis, significant broadening of the beta and beta' resonances in H-1 NMR and neutral electrolytic behavior are reported and taken together, these parameters can now unequivocally serve as criteria to detect any tridentate coordination mode of the tripod in the chemistry of dichloroferrous complexes with tris-(2-pyridylmethyl)amine type ligands. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.026