[AuCl(3,5-dibromo-9-(4-isocyanophenyl)carbazole)] | 1228784-85-7

• 英文名称: [AuCl(3,5-dibromo-9-(4-isocyanophenyl)carbazole)]
• CAS: 1228784-85-7
• 化学式: C₁₉H₁₀AuBr₂ClN₂
• 分子量: 658.529
• InChiKey: CCEOOPZWZRIHOT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  AuCl(THF) 、 3,6-dibromo-9-(4-isocyanophenyl)carbazole 以 二氯甲烷 为溶剂， 以63%的产率得到[AuCl(3,5-dibromo-9-(4-isocyanophenyl)carbazole)]
  参考文献：
  名称：

  Synthesis and Characterization of Gold(I) Complexes with 9‐(4‐Isocyanophenyl)carbazole or 9‐Ethyl‐3‐isocyanocarbazole Ligands

  摘要：

  AbstractThe carbazole derivatives 9‐(4‐isocyanophenyl)carbazole, 3,6‐dibromo‐9‐(4‐isocyanophenyl)carbazole, and 9‐ethyl‐3‐isocyanocarbazole were prepared and used to synthesize [AuX(CN‐carbazole)] (X = Cl, C6F5, C6F4‐OEt‐p) gold complexes. The X‐ray structures of [Au(C6F4‐OEt‐p){9‐(4‐isocyanophenyl)carbazole}] and [Au(C6F5)(9‐ethyl‐3‐isocyanocarbazole)], and the luminescent properties of the ligands and the complexes in the solid state, in solution at room temperature, and in frozen solution of chloroform at 77 K were determined. All the gold complexes show a redshift in the emissions relative to that of the free ligand. The presence of electron‐withdrawing substituents in 3,6‐dibromo‐9‐(4‐isocyanophenyl)carbazole quenches the luminescence, but with the introduction of a gold atom some luminescence is recovered.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900692