[Pd(C(=N(2,6-dimethylphenyl))CH3)(4,4'-di-tert-butyl-2,2'-dipyridyl)(N(CH3)=CHPh)][BF4] | 582294-83-5

• 英文名称: [Pd(C(=N(2,6-dimethylphenyl))CH3)(4,4'-di-tert-butyl-2,2'-dipyridyl)(N(CH3)=CHPh)][BF4]
• CAS: 582294-83-5
• 化学式: BF₄*C₃₆H₄₅N₄Pd
• 分子量: 727.005
• InChiKey: DHJLOACSZDHGBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Pd(C(=N(2,6-dimethylphenyl))CH3)(4,4'-di-tert-butyl-2,2'-dipyridyl)(N(CH3)=CHPh)][BF4] 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以68%的产率得到[Pd(4,4'-di-tert-butyl-2,2'-dipyridyl)(η2-[Pd(4,4'-di-tert-butyl-2,2'-dipyridyl)(N(2,6-dimethylphenyl)C(Me)C(Me)NXy)])][BF4]2
  参考文献：
  名称：

  Synthesis and Structural Characterization of a Novel Dipalladium Complex with an Unprecedented PdCN Bonding Motif

  摘要：

  Removal of the chloride atom from Pd{C-(=NXy)CH3}(Cl)(Bu(2)(t)bipy) initiates a series of reactions that lead to the formation of the novel dipalladium complex [Pd(Bu(2)(t)bipy) {eta(2)-[pd(Bu(2)(t)bipy) {N(Xy)=C(CH3)-C(CH3)=NXy}]}][BF4](2). In this process, two imidoyl groups undergo a C-C coupling reaction generating a bis-imino ligand that coordinates to two palladium centers, one of which is bound to a C-N bond of the ligand giving an unprecedented three-membered PdCN ring.

  DOI：

  10.1021/om030235u
• 作为产物：
  描述：

  2,6-二甲基苯基异腈 以 二氯甲烷 为溶剂， 生成 [Pd(C(=N(2,6-dimethylphenyl))CH3)(4,4'-di-tert-butyl-2,2'-dipyridyl)(N(CH3)=CHPh)][BF4]
  参考文献：
  名称：

  Synthesis and Structural Characterization of a Novel Dipalladium Complex with an Unprecedented PdCN Bonding Motif

  摘要：

  Removal of the chloride atom from Pd{C-(=NXy)CH3}(Cl)(Bu(2)(t)bipy) initiates a series of reactions that lead to the formation of the novel dipalladium complex [Pd(Bu(2)(t)bipy) {eta(2)-[pd(Bu(2)(t)bipy) {N(Xy)=C(CH3)-C(CH3)=NXy}]}][BF4](2). In this process, two imidoyl groups undergo a C-C coupling reaction generating a bis-imino ligand that coordinates to two palladium centers, one of which is bound to a C-N bond of the ligand giving an unprecedented three-membered PdCN ring.

  DOI：

  10.1021/om030235u