[RhCl(COD)]2(μ2-(1,3-(PPh2CH2)2C6H4)) | 271598-15-3

• 英文名称: [RhCl(COD)]2(μ2-(1,3-(PPh2CH2)2C6H4))
• CAS: 271598-15-3
• 化学式: C₄₈H₅₂Cl₂P₂Rh₂
• 分子量: 967.605
• InChiKey: CLMSCKSJCGWAPY-XTSSNGSKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 1,3-双(二苯基膦甲基)苯 以 异丙醇 为溶剂， 以42%的产率得到RhH(1,3-(PPh2CH2)2C6H4)(μ-Cl)2Rh(COD)
  参考文献：
  名称：

  Preparation of some dinuclear rhodium complexes with the orthometallated ligand [2,6-(PPh2CH2)2C6H3]− and their catalytic activity for polymerization of phenylacetylene

  摘要：

  Reaction of 1.3-(PPh2CH2)(2)C6H4 (PCHP) with [RhCl(COD)](2) in isopropanol produced a mixture of dinuclear complexes [RhCl(COD)](2)(mu(2)-PCHP), RhH(PCP)(mu-Cl)(2)Rh(COD), and [RhHCl(PCP)](2)(mu(2)-PCHP). Reaction of RhH(PCP)(mu-Cl)(2)Rh(COD) with CCl4 produced RhCl(PCP)(mu-Cl)(2)Rh(COD). The solid-state structure of the latter complex has been characterized by X-ray diffraction. With the exception of [RhHCl(PCP)](2)(mu(2)-PCHP), all the dinuclear complexes in THF are catalytically active for the polymerization of phenylacetylene. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00710-x