[C4H7Pd(PhOCH2COOEt-κ2-O,O)]BF4 | 181023-60-9

• 英文名称: [C4H7Pd(PhOCH2COOEt-κ2-O,O)]BF4
• CAS: 181023-60-9
• 化学式: BF₄*C₁₄H₁₉O₃Pd
• 分子量: 428.528
• InChiKey: GGSJJERDDSILCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2-methylallyl)palladium-chloride dimer 、 苯氧乙酸乙酯 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以88%的产率得到[C4H7Pd(PhOCH2COOEt-κ2-O,O)]BF4
  参考文献：
  名称：

  Hemilabile ligands in palladium catalysed CC linkages: the effect of the donor atom in the codimerisation of styrene with ethylene

  摘要：

  Cationic eta(3)-2-methylallylpalladium(II) complexes with potentially hemilabile ligands XCH(2)COOEt (X = NPh(2), PPh(2), OPh, SPh) or methylpicolinate have been prepared and their catalytic properties in the codimerisation of styrene with ethylene have been investigated. The catalytic activity decreases in the order of decreasing trans influence of X: P >> N approximate to O > S > pyr. The relationship between catalytic activity and spectroscopic properties of the complexes is discussed.

  DOI：

  10.1016/1381-1169(96)00067-2