[silver(I)(2,2'-bipyridyl-6,6'-dicarbonyl-A,D-capped 6A,6D-diamino-6A,6D-dideoxy-hexadeca-O-methyl-α-cyclodextrin)][BF4] | 354111-32-3

• 英文名称: [silver(I)(2,2'-bipyridyl-6,6'-dicarbonyl-A,D-capped 6A,6D-diamino-6A,6D-dideoxy-hexadeca-O-methyl-α-cyclodextrin)][BF4]
• CAS: 354111-32-3
• 化学式: Ag*BF₄*C₆₄H₉₈N₄O₃₀
• 分子量: 1598.16
• InChiKey: ZRQVEPPBCBZFSP-FDYIOXHASA-N

反应信息

• 作为产物：
  描述：

  silver tetrafluoroborate 、 2,2'-bipyridyl-6,6'-dicarbonyl-A,D-capped 6A,6D-diamino-6A,6D-dideoxy-hexadeca-O-methyl-α-cyclodextrin 以 乙腈 为溶剂， 以98%的产率得到[silver(I)(2,2'-bipyridyl-6,6'-dicarbonyl-A,D-capped 6A,6D-diamino-6A,6D-dideoxy-hexadeca-O-methyl-α-cyclodextrin)][BF4]
  参考文献：
  名称：

  Anchoring a helical handle across a cavity: the first 2,2′-bipyridyl-capped α-cyclodextrin capable of encapsulating transition metals

  摘要：

  The reaction of 6,6 ' -bis(chlorocarbonyl)-2,2 ' -bipyridine with 6A,6D-diamino-6A,6D-dideoxy-2(A),2(B),2(C),2(D),2(E),2(F),3(A),3(B), 3(C),3(D),3(E),3(F),6(B),6(C),6(E),6(F)-hexadeca-O-methylcyclo maltohexaose (1) afforded the corresponding capped cyclodextrin derivative (LH) in which the nitrogen atoms are forced to point towards the cavity interior. As shown by a single crystal X-ray diffraction study, the capping handle adopts a helical shape. In silver(I) and palladium(II) complexes derived from LH, the metal centre is encapsulated and positioned at the entrance of the CD receptor. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00727-6