[N,N'-bis(quinoline-2-methylene)diiminocyclohexane]benzylmanganese(II) chloride | 928757-47-5

• 英文名称: [N,N'-bis(quinoline-2-methylene)diiminocyclohexane]benzylmanganese(II) chloride
• CAS: 928757-47-5
• 化学式: C₃₃H₃₁ClMnN₄
• 分子量: 574.027
• InChiKey: HORHMGBVNUGFQK-YICTUOAMSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [N,N'-bis(quinoline-2-methylene)diiminocyclohexane]manganese(II) dichloride 、 苄基溴化镁 以 乙醚 为溶剂， 以83%的产率得到[N,N'-bis(quinoline-2-methylene)diiminocyclohexane]benzylmanganese(II) chloride
  参考文献：
  名称：

  Manganese(II) Complexes in Ethene Polymerization

  摘要：

  A series of manganese(II) dichloro complexes made in situ and bearing mainly various nitrogen ligands was studied with a parallel screening method in order to identify catalytically active complexes for ethene polymerization using methylaluminoxane (MAO) as a cocatalyst. From the series two of the most active octahedral manganese(II) complexes, those bearing tetradentate nitrogen ligands with chiral bridges, [N, N'-bis( quinoline-2-methylene) diiminocyclohexane] MnCl2 (1) and {N,N'-(6,6'-dimethylbiphenyl-2,2'-diyl)-bis[(2- pyridyl) methyl] diimine} MnCl2 (2), were selected for more detailed studies. According to their solid-state structures, it is common for these C-2-symmetric manganese complexes to have a distorted-octahedral coordination geometry where chlorides occupy cis positions with wide Cl-Mn-Cl angles (132-135). The highest activity in ethene polymerization (67 kg of PE/((mol of Mn) h)) was obtained with 1/MAO at 80 degrees C. Furthermore, the alkylation of 1 and 2 with MeMgBr and (benzyl) MgBr was investigated, but only their monobenzyl derivatives were isolable.

  DOI：

  10.1021/om0608105