| 263356-46-3

• CAS: 263356-46-3
• 化学式: C₁₂H₁₈Cl₂Cu₂N₂O₄S₂
• 分子量: 516.416
• InChiKey: VKBFGENNALEMBD-MGMKKPHLSA-J

反应信息

• 作为产物：
  描述：

  N,N'-bis(1-ethoxycarbonylethyl)ethanedithioamide 、 copper dichloride 以 乙醇 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  THE COORDINATING BEHAVIOR OF N,N′-BIS(1-ETHOXYCARBONYLETHYL)- ETHANEDITHIOAMIDE TOWARDS Pd(II), Pt(II), AND Cu(II)

  摘要：

  The coordinating behaviour of N,N'-bis(1-ethoxy-carbonylethyl)ethanedithioamide (H2L) was studied by preparing and characterising the complexes of the types [M(HL)(2)], [M(H2L)(2)]Cl-2 (M = Pd(II) and Pt(II)) and [Cu-2(L)X-2] (X = Cl and Br). Their structures were studied employing C-13 NMR, EPR, IR and UV-VIS spectral methods. In the [M(HL)(2)] and [M(H2L)(2)]Cl-2 complexes the ligand acts as a bidentate and coordinates through sulfur, giving a square-planar MS4 surrounding, whereas in the [CU2(L)X-2] complexes the ligand acts as a bis(tridentate) with N, S, O-cordination to two copper(II) ions. The electronic and EPR spectra of the [Cu-2(L)X-2] complexes indicate a distorted square-planar symmetry around the Cu(II) ions.

  DOI：

  10.1081/sim-100104789