名称:
Reactions of halides with trans-[Re(CO)4(MeCN)(NS)][AsF6]2: syntheses and structure of trans-[Re(CO)4(Cl)(NS)][AsF6] and [(OC)5ReNS–NS–N[Re(CO)5]S{N–SNRe(CO)5}–CH2–CH2][AsF6]2, an unusual trinuclear bis(thiazyl)rhenium complex
摘要:
From the reactions of trans-[Re(CO)(4)(MeCN)(NS)][AsF6](2) with CsCl, trans-[Re(CO)(4)Cl(NS)][AsF6]. MeCN 2 is formed, and with CsF [{Re(CO)(5)}(3)(C2H2N5S4)][AsF6](2) 3 is isolated; the X-ray crystal structures of 2 and 3 are reported.