| 313706-06-8

• CAS: 313706-06-8
• 化学式: C₂₄H₃₁Cl₂N₃OTi
• 分子量: 496.316
• InChiKey: JRWGDSBHWJZJDB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-叔丁基吡啶 、 、 四氯化钛 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  A study of ortho- and para-siloxyanilines for the synthesis of mono-, bi-, and tetra-nuclear early transition metal–imido complexes

  摘要：

  The siloxyanilines o-Me(3)SiOC(6)H(4)NH(2) (1) and p-RMe(2)SiOC(6)H(4)NH(2) (R = H (2); R = Me (3)), and their N-silylated derivatives p-Me(3)SiOC(6)H(4)NHSiMe(3) (4) and p-Me(3)SiOC(6)H(4)N(SiMe(3))(2) (5) have been prepared from ortho- or para-aminophenol and used in the synthesis of imido complexes. Thus, binuclear [{Ti(eta (5)-C(5)H(5))Cl} {mu -NC(6)H(4)(p-OSiMe(3))}](2) (6) and mononuclear [TiCl(2){NC(6)H(4)(p-OSiMe(3))}(py)(3)] (7) imido complexes have been obtained from the reaction of 3 and [Ti(eta (5)-C(5)H(5))Cl(3)] or [TiCl(2)(N'Bu)(py)(3)], respectively. In contrast, the reaction of 1 with TiCl(4) and 'Bupy affords the titanocycle [TiCl(2){OC(6)H(4)(o-NH)-N,O}('Bupy)(2)] (8). Compound 5 has also been used to prepare the niobium imide complex [NbCl(3){NC(6)H(4)(p-OSiMe(3))}(MeCN)(2)] (9), by its reaction with NbCl(5) in CH(3)CN. These findings have been applied to the synthesis of polynuclear systems. Thus, chlorocarbosilane Si[CH(2)CH(2)CH(2)Si(Me)(2)Cl], (CS-Cl) has been functionalized with the ortho- and para-aminophenoxy groups to give 10 and 11, respectively. The use of 11 has allowed the formation of the tetranuclear compound 12. Attempts to synthesize terminal imido titanium complexes from 10 and TiCl(4) in the presence of 'Bupy and Et(3)N, give complex 8 and carbosilane CS-Cl. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00391-0