| 173722-86-6

• CAS: 173722-86-6
• 化学式: C₂₈H₆₄In₂P₂
• 分子量: 692.404
• InChiKey: YZNWWAADNKKCRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trineopentylindium 、 二乙基膦 以 苯 为溶剂， 以97.13%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of a Series of Organoindium Phosphides, Including Molecular Structures of [(Me3CCH2)2InPEt2]2 and [(Me3CCH2)2InP(H)(C6H11)]3

  摘要：

  A series of organoindium phosphides including (Me(3)CCH(2))(2)InPRR' (R = R' = Et, C6H11; R = C6H11, R' = H; R = Me, R' = Ph) and (Me(3)SiCH(2))(2)InP(Me)Ph have been prepared and characterized. The characterization data include partial elemental analyses (C, H), H-1 and P-31 NMR and IR spectral studies, physical properties, cryoscopic molecular weight studies (with the exception of (Me(3)CCH(2))(2)InP(C6H11)(2)), and X-ray structural studies of [(Me(3)CCH(2))(2)-InPEt(2)](2) and [(Me(3)CCH(2))(2)InP(H)(C6H11)](3). The compound (Me(3)CCH(2))(2)InPEt(2) is observed to be a dimer in benzene solution; (Me(3)CCH(2))(2)InP(H)(C6H11) exists as a dimer-trimer equilibrium mixture, whereas (Me(3)CCH(2))(2)InP(Me)(Ph) and (Me(3)SiCH(2))2InP(Me)(Ph) are trimers. NMR studies are consistent with (Me(3)CCH(2))(2)InP(C6H11)(2) being a dimer in benzene solution, but the concentration was too low to confirm the conclusion by cryoscopic molecular weight studies. The compound [(Me(3)CCH(2))(2)InPEt(2)](2) contains a planar In2P2 core with In-P distances of 2.623(2) and 2.641(2) Angstrom. The compound [(Me(3)CCH(2))2InP(H)(C6H11)](3) has an In3P3 six-membered ring which is in the twist-boat conformation with In-P distances ranging from 2.613(3) to 2.659(2) Angstrom.

  DOI：

  10.1021/om00007a052