[ZrCl2(N,N'-phenylenebis(5-methoxysalicylideneiminate))] | 866563-16-8

• 英文名称: [ZrCl2(N,N'-phenylenebis(5-methoxysalicylideneiminate))]
• CAS: 866563-16-8
• 化学式: C₂₂H₁₈Cl₂N₂O₄Zr
• 分子量: 536.526
• InChiKey: JEASVNQTTUMAFQ-IRGXHNTLSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ZrCl2(N,N'-phenylenebis(5-methoxysalicylideneiminate))(THF)] 以 甲苯 为溶剂， 生成 [ZrCl2(N,N'-phenylenebis(5-methoxysalicylideneiminate))]
  参考文献：
  名称：

  Preparation and structures of 6- and 7-coordinate salen-type zirconium complexes and their catalytic properties for oligomerization of ethylene

  摘要：

  A series of salen-type zirconium complexes of the general formula LZrCl2 (L = N,N '-ethylenebis(salicylideneiminate), 3a; N,N '-ethylenebis(3,5-di-tert -butylsalicylideneiminate), 3b; N,N '-ethylenebis(5-methoxysalicylidenciminate), 3e; N,N '-o-phethylenebis(5-chlorosalicylideneiminate), 3d; N,N '-ethylenebis(5-nitrosalicylideneiminate), 3e; N,N '-o-phenylenebis(salicylideneiminate), 4a; N,N '-o-phenylenebis(3,5-di-tert-butylsalicylideneiminate), 4b; N,N '-o-phenylenebis(5-methoxysalicylideneiminate), 4c; N,N '-o-phenylenebis(5-chloro-salicylideneiminate), 4d) were prepared. The crystal structures of 6- and 7-coordinate zirconium complexes 4b and [4b center dot OCMe2] were determined by X-ray crystallography, which reveals that a salen-type zirconium complex possesses a labile coordination site on the Zr center with a relatively stable framework and that the coordination and the dissociation of O-donor molecules occur readily at this site. The catalytic properties of 3(a-e) and 4(a-d) were studied for ethylene oligomerization in combination with Et2AlCl as co-catalyst. Complex 3c featuring a methoxy-substituted salen ligand displayed higher activity than its analogous precursors having chloro and nitro groups as substituents. The catalytic reactions by 3(a-e) and 4(a-d) gave C-4-C-10 olefins and low-carbon linear (alpha-olefins in good selectivity. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.027