cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(tBu2bipy)]PF6 | 1233766-60-3

• 英文名称: cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(tBu2bipy)]PF6
• CAS: 1233766-60-3
• 化学式: C₃₀H₃₇F₂N₄OPtS*F₆P
• 分子量: 879.757
• InChiKey: YCKGWSSFJVPYDH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 dichloro(4,4'-di-tert-butyl-2,2'-bipyridine)platinum(II) 、 N-(diethylcarbamothioyl)-2,6-difluorobenzamide 以 乙腈 为溶剂， 以76%的产率得到cis-[Pt(κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2)(tBu2bipy)]PF6
  参考文献：
  名称：

  Cationic palladium(II), platinum(II) and ruthenium(II) complexes containing a chelating difluoro-substituted thiourea ligand

  摘要：

  The fluorine substituted thiourea 2,6-F2C6H3C(O)NHC(S)NEt2 was prepared in good yield from the reaction of 2,6-F2C6H3C(O)Cl with KSCN and Et2NH in acetone. Using this compound several heteroleptic, monocationic Pd(II), Pt(II) and Ru(II) complexes of the type cis-[M{kappa S-2,O-2,6-F2C6H3C(O)NC(S)NEt2}(L)] PF6 [M = Pt, Pd; L = (Ph3P)(2), 'Bu(2)bipy, 1,10-phen] as well as [Ru(eta(6)-p-cym){kappa S-2,O-2.6-F2C6H3C(O)NC(S)-NEt2}(Ph-3)]PF6 were prepared in high yields. The compounds were characterised by spectroscopic methods and, in one case, by single crystal X-ray diffraction. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.03.010