Ru(II)(tetraphenylporphyrin(2-))CO(1-(p-nitrophenyl)-5-methyl-5-phenyl-Δ-1,2,3-triazoline) | 866596-10-3

• 英文名称: Ru(II)(tetraphenylporphyrin(2-))CO(1-(p-nitrophenyl)-5-methyl-5-phenyl-Δ-1,2,3-triazoline)
• CAS: 866596-10-3
• 化学式: C₆₀H₄₂N₈O₃Ru
• 分子量: 1024.12
• InChiKey: UNSUAWXYLJSEJN-KGAZGDRTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(II)(tetraphenylporphyrin(2-))CO(1-(p-nitrophenyl)-5-methyl-5-phenyl-Δ-1,2,3-triazoline) 、 异氰酸叔丁酯 以 not given 为溶剂， 生成 [ruthenium(II) (meso-tetraphenylporphinate)(t-butyl isocyanide)2]
  参考文献：
  名称：

  Origin of the Deactivation in Styrene Aziridination by Aryl Azides, Catalyzed by Ruthenium Porphyrin Complexes. Structural Characterization of a Δ²-1,2,3-Triazoline Ru^II(TPP)CO Complex

  摘要：

  The reaction of Ru(TPP)CO (TPP = dianion of tetraphenylporphyrin) with 1-(p-nitrophenyl)-5-methyl-5-phenyl- 1,2,3-triazoline yielded a Delta(2)-1,2,3-triazoline ruthenium(II) porphyrin complex, which is responsible for the catalyst deactivation in the aziridination reaction of (x-methylstyrene by p-nitrophenyl azide.

  DOI：

  10.1021/om050244y
• 作为产物：
  描述：

  carbonyl(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) 、 1-(3,5-bis(trifluoromethyl)phenyl)-5-methyl-5-phenyl-1,2,3-triazoline 以 苯 为溶剂， 以85%的产率得到Ru(II)(tetraphenylporphyrin(2-))CO(1-(p-nitrophenyl)-5-methyl-5-phenyl-Δ-1,2,3-triazoline)
  参考文献：
  名称：

  Origin of the Deactivation in Styrene Aziridination by Aryl Azides, Catalyzed by Ruthenium Porphyrin Complexes. Structural Characterization of a Δ²-1,2,3-Triazoline Ru^II(TPP)CO Complex

  摘要：

  The reaction of Ru(TPP)CO (TPP = dianion of tetraphenylporphyrin) with 1-(p-nitrophenyl)-5-methyl-5-phenyl- 1,2,3-triazoline yielded a Delta(2)-1,2,3-triazoline ruthenium(II) porphyrin complex, which is responsible for the catalyst deactivation in the aziridination reaction of (x-methylstyrene by p-nitrophenyl azide.

  DOI：

  10.1021/om050244y