[manganese(II)(bromo)(tris(3,5-diisopropyl-1-pyrasolyl)methane)(CH3OH)2]Br | 1009339-11-0

• 英文名称: [manganese(II)(bromo)(tris(3,5-diisopropyl-1-pyrasolyl)methane)(CH3OH)2]Br
• CAS: 1009339-11-0
• 化学式: Br*C₃₀H₅₄BrMnN₆O₂
• 分子量: 745.544
• InChiKey: FKJNUPIMDTXILV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 manganese(II) bromide tetrahydrate 、 tris(3,5-diisopropyl-1-pyrazolyl)methane 以 甲醇 、 二氯甲烷 为溶剂， 以73%的产率得到[manganese(II)(bromo)(tris(3,5-diisopropyl-1-pyrasolyl)methane)(CH3OH)2]Br
  参考文献：
  名称：

  Manganese(II) halogeno complexes with neutral tris(3,5-diisopropyl-1-pyrazolyl)methane ligand: Synthesis and ethylene polymerization

  摘要：

  Manganese(II) halogeno complexes containing a neutral tris(3,5-diisopropyl-l-pyrazolyl)methane (referred to as Ll') ligand have been examined on their catalytic performance in ethylene polymerization and ethylene/l-hexene copolymerization. The activities of [Mn(Cl-2)(Ll')] (a) and [Mn(Br)(Ll')](Br) (b) activated by Al(i-Bu)(3)/(Ph3C)[B(C6F5)4] for ethylene polymerization go up to 1600 and 840 kg mol(cat)(-1) h(-1) with a bimodal molecular weight distribution (MwMn) of 4.1 and 4.2, respectively. These results are different from the corresponding manganese(II) complexes with hydrotris(pyrazolyl)borate anion. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.12.043