[(η5-1,2,3,4,5,6,7,8,9-nonamethyl-9H-fluorene(-1H))Mn(CO)3] | 937383-80-7

• 英文名称: [(η5-1,2,3,4,5,6,7,8,9-nonamethyl-9H-fluorene(-1H))Mn(CO)3]
• CAS: 937383-80-7
• 化学式: C₂₅H₂₇MnO₃
• 分子量: 430.426
• InChiKey: UJNLLDNGHHMBKD-DEXDRMDJSA-N

反应信息

• 作为产物：
  描述：

  [(η6-1,2,3,4,5,6,7,8,9-nonamethyl-9H-fluorene)Mn(CO)3]PF6*0.5CH2Cl2 在 t-BuOK 作用下， 以 二氯甲烷 为溶剂， 以66.8%的产率得到[(η5-1,2,3,4,5,6,7,8,9-nonamethyl-9H-fluorene(-1H))Mn(CO)3]
  参考文献：
  名称：

  The synthesis of [(η6-Flu∗H)Mn(CO)3]PF6, and its deprotonation to yield a novel coordination mode of fluorene

  摘要：

  The synthesis of [(eta(6)-Flu*H)Mn(CO)(3)]PF6 is reported. The complex may be deprotonated to give a neutral zwitterionic complex. Instead of deprotonation at the 9-position, as seen in the non-methylated complex, deprotonation of a ring methyl is observed. This yields a previously unknown coordination mode of fluorene, and may be explained on both electronic and steric grounds. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.01.025