| 346713-22-2

• CAS: 346713-22-2
• 化学式: C₃₀H₃₀IrN₃OP*F₆P
• 分子量: 816.746
• InChiKey: UAVLMHVPZAIBBM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  S*c,S*p1-Ir(cyclooctadiene)(PPh2-C6H4CHCH3OCH2C5H4N)(1+)PF6(1-) 以 neat (no solvent) 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  Acetonitrile Accelerated Stereoselective C–H Bond Activation of the Cationic Ir(I) Complex Having the PN/CH₃Heterochelate Hybrid Ligand

  摘要：

  The cationic iridium(I) complex having a heterochelate ligand, [Ir(cod)(PN/CH3)]PF6 {PN/CH3 = o-Ph2PC6H4CH(CH3)OCH2(C5H4N-2)} (3) was prepared and characterized. Complex 3 underwent stereoselective facile activation of the benzylic C–H bond in CH3CN at 50 °C to produce the oxidative addition product, a hydrido alkyl complex fac-4 after displacement of COD by 2 molecules of CH3CN. The initially generated fac-4 isomerized gradually to give the geometrical isomer selectively mer-4 in CH3CN.

  DOI：

  10.1246/cl.2001.300