| 150955-50-3

• CAS: 150955-50-3
• 化学式: C₄₈H₄₀P₃PtS*ClO₄
• 分子量: 1036.36
• InChiKey: VKBCDHAUAVHLBK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Pt(acac)(PPh3)2]ClO4 、 diphenylphosphane sulfide 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Different co-ordination modes of the ligand [SPPh₂]^–in complexes of Pd^IIand Pt^II. Crystal structures of [{Pd(µ-SPPh₂)(C₆F₅)(PPh₃)}₂] and [Pd(SPPh₂)(PPh₃)₂]ClO₄·CH₂Cl₂

  摘要：

  The neutral complexes [{M(mu-SPPh2)(C6F5)(PR3)}2] (M = Pd or Pt; PR3 = PPh3 or PPh2Et) containing the P,S-bridging [SPPh2]- have been synthesised by reaction of the corresponding acetylacetonate (acac) derivatives [M(C6F5)(acac-O,O')(PR3)] with HP(S)Ph2. However, the reaction of the cationic complexes [M(acac-O,O')(PPh3)2]ClO4 (M = Pd or Pt) with HP(S)Ph2 affords mononuclear [M(SPPh2)(PPh3)2]ClO4 in which the [SPPh2]- ligand is co-ordinated as a P,S-chelate. The anionic complex [NBu4]2[{Pd(mu-SPPh2)(C6F5)2}2] has also been synthesised. The crystal structures of [{Pd(mu-SPPh2)(C6F5)(PPh3)}2] and [Pd(SPPh2)(PPh3)2]ClO4.CH2Cl2 have been determined by X-ray diffraction methods; the former adopts a boat conformation.

  DOI：

  10.1039/dt9930002147