[Ru(η6-C10H14)(PPh3)Cl((CN)2C6H4)]PF6 | 302911-45-1

• 英文名称: [Ru(η6-C10H14)(PPh3)Cl((CN)2C6H4)]PF6
• 英文别名: benzene-1,4-dicarbonitrile;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene;triphenylphosphane;hexafluorophosphate
• CAS: 302911-45-1
• 化学式: C₃₆H₃₃ClN₂PRu*F₆P
• 分子量: 806.132
• InChiKey: WWBQYMUSLRCUAV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  对苯二腈 、 ammonium hexafluorophosphate 、 [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] 以 甲醇 为溶剂， 以80%的产率得到[Ru(η6-C10H14)(PPh3)Cl((CN)2C6H4)]PF6
  参考文献：
  名称：

  Synthesis and spectroscopic properties of cationic Ru(II) arene complexes [Ru(η6-arene)(P)Cl(L)]+. (P=PPh3, PEt3, MePPri2 and L=4-cyanopyridine or 1,4-dicyanobenzene)

  摘要：

  Reactions of [Ru(eta(6)-arene)(P)Cl-2] (P = PPh3, PEt3 or MePPr'(2)) with organonitriles 4-cyanopyridine or 1,4-dicyanobenzene (referred hereafter as CNPy or DCB) in methanol, in the presence of NH4PF6, gives the cationic arene complexes [Ru(eta(6)-arene)(P)Cl(L)](+) (L = CNPy or DCB). The reaction products have been characterized by physico-chemical methods viz., elemental analyses, IR, H-1- C-13-, P-31-NMR, electronic and FAB mass spectra. The spectral data of the complexes revealed the presence of a pendant nitrile group. These could behave as potential metallo-ligands and could find wide application in the syntheses of homo- or heterobimetallic mixed valence bridged complexes. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00258-8