[trans-PtCl4(NH=C(Me)ON=C(NH2)C6H5)2] | 285141-29-9

• 英文名称: [trans-PtCl4(NH=C(Me)ON=C(NH2)C6H5)2]
• CAS: 285141-29-9
• 化学式: C₁₈H₂₂Cl₄N₆O₂Pt
• 分子量: 691.304
• InChiKey: OBRHWJFHBJDPIZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-{Pt(MeCN)2Cl4} 、 苯甲酰胺肟 以 二氯甲烷 为溶剂， 以84%的产率得到[trans-PtCl4(NH=C(Me)ON=C(NH2)C6H5)2]
  参考文献：
  名称：

  Iminoacylation

  摘要：

  Addition of chloro- and amidoximes (RRC)-C-1=NOH (R/R-1 = Cl/Ph, Cl/C6H4-p-Me, Cl/C6H4-p-NO2, NH2/Ph) to the acetonitrile ligands in trans-[PtCl4(MeCN)(2)] proceeds much slower as compared to ketoximes with donor substituents R/R-1 [V.Yu. Kukushkin, T.B. Pakhomova, Yu.N. Kukushkin, R. Herrmann, G. Wagner, A.J.L. Pombeiro, Inorg. Chem. 37 (1998) 6511] and leads to the complexes with iminoacylated species [ligating (alkylideneaminooxy)imines] trans-[PtCl4 (NH=C(Me)ON=CRR1)(2)]. X-ray crystal structure determination of two iminoacylated compounds (R/R-1 = Cl/C6H4-p-Me, Cl/C6H4-p-NO2) disclosed their overall trans geometry with monodentate organic ligands in E-conformation and indicated =NH...N hydrogen bonding between the imino H atom and the oxime nitrogen. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00556-3