cis-[NiCl2(Ph2PN(Ph)N(Ph)PPh2-P,P)] | 1201394-01-5

• 英文名称: cis-[NiCl2(Ph2PN(Ph)N(Ph)PPh2-P,P)]
• CAS: 1201394-01-5
• 化学式: C₃₆H₃₀Cl₂N₂NiP₂
• 分子量: 682.191
• InChiKey: RNNSTNWZWRNRQT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化镍二甲氧基乙烷 、 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine 以 CH₂Cl₂ 为溶剂， 以85%的产率得到cis-[NiCl2(Ph2PN(Ph)N(Ph)PPh2-P,P)]
  参考文献：
  名称：

  Synthesis, Coordination Chemistry, and Catalysis of the First 1,2-Bis(diphenylphosphino)-1,2-diphenylhydrazine, Ph₂PN(Ph)N(Ph)PPh₂

  摘要：

  The reaction of chlorodiphenylphosphine with dilithiophydrazobeneze gave 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine, [PPh2N(Ph)N(Ph)PPb2] (1). Treatment of 1 with NiCl2(DME), PdCl2(PhCN)(2), and PtCl2(COD) resulted in the formation of complexes of the type cis-[MCl2-{Ph2PN(Ph)N(Ph)PPh2}] (M = Ni (3), Pd (4), Pt (5)). The molecular Structures of the starting ligand I and the complexes 3, 4, and 5 have been determined by X-ray diffraction, The ligand 1 and its Ni(II) complex 3 were evaluated for their catalytic activity in the oligo-/polymerization of ethylene using methylaluminoxane (MAO) and triethylaluminium (TEA) as cocatalyst.

  DOI：

  10.1021/om900925b