2,6-dibenzhydryl-N-(2-(2,6-dibenzhydryl-4-chlorophenylimino)acetonaphthylenylidene)-4-benzenaminopalladium(II) dichloride | 1388630-78-1

• 英文名称: 2,6-dibenzhydryl-N-(2-(2,6-dibenzhydryl-4-chlorophenylimino)acetonaphthylenylidene)-4-benzenaminopalladium(II) dichloride
• CAS: 1388630-78-1
• 化学式: C₇₆H₅₄Cl₄N₂Pd
• 分子量: 1243.51
• InChiKey: HVVJDXSOCLKKQL-COBYYSCXSA-L

反应信息

• 作为产物：
  描述：

  palladium chloride*2MeCN 、 2,6-dibenzhydryl-N-(2-(2,6-dibenzhydryl-4-chlorophenylimino)acetonaphthylenylidene)-4-benzenamine 以 二氯甲烷 为溶剂， 以51.3%的产率得到2,6-dibenzhydryl-N-(2-(2,6-dibenzhydryl-4-chlorophenylimino)acetonaphthylenylidene)-4-benzenaminopalladium(II) dichloride
  参考文献：
  名称：

  2,6-Dibenzhydryl-N-(2-aryliminoacenaphthylenylidene)-4-chlorobenzenamino-palladium dichlorides: Synthesis, characterization, and use as catalysts in the Heck-reaction

  摘要：

  A series of 2,6-dibenzhydryl-N-(2-aryliminoacenaphthylenylidene)-4- chlorobenzenaminopalladium(II) chloride complexes (C1-C6) were prepared and fully characterized by FT-IR and NMR spectroscopy, and by elemental analysis. The molecular structures of representative complexes C2 and C6 were confirmed as square planar at the palladium center by single crystal X-Ray diffraction. All palladium complexes exhibited good activity in the Heck cross-coupling reaction with conversions greater than 90%. Catalytic activity trends were attributed to differences in the solubility of the pre-catalysts; palladium complexes bearing more soluble alkyl-substituents performed with higher catalytic activities. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.05.015