[Na(18-crown-6)(H2O)2][PtCl4(glycinate)] * 18-crown-6 | 189289-56-3

• 英文名称: [Na(18-crown-6)(H2O)2][PtCl4(glycinate)] * 18-crown-6
• CAS: 189289-56-3
• 化学式: C₂H₄Cl₄NO₂Pt*C₁₂H₂₄O₆*C₁₂H₂₈NaO₈
• 分子量: 998.61
• InChiKey: YWEPNOCYPTUNLD-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Na(18-crown-6)]2[PtCl6] * 3 H2O 、 聚甘氨酸 以 水 为溶剂， 以27%的产率得到[Na(18-crown-6)(H2O)2][PtCl4(glycinate)] * 18-crown-6
  参考文献：
  名称：

  The crown ether influence on ligand exchange reactions of Na2PtCl6 with glycine and D-(+)-alanine; synthesis and characterization of platinum(IV) amino acid complexes

  摘要：

  The reaction of Na2PtCl6 with glycine in water yields cis-[PtCl2(gly)(2)] (1). [Na(18-cr-6)](2)[PtCl6]. 3H(2)O reacts with glycine and D-(+)-alanine in water to give [Na(18-cr-6)(H2O)(2)][PtCl4(gly)].(18-cr-6) (2) and [Na(18-cr-6)][PtCl4(ala)] (3), respectively. Cis-[PtCl4(glyH)(2)].4(18-cr-6) (4) and cis-[PtCl4(alaH)(2)].(18-cr-6) (5), respectively, are formed when the reaction mixture is irradiated with light from a halogen lamp. All complexes were characterized by microanalysis as well as by NMR, IR and Raman spectroscopy revealing that in complexes 1-3 the glycinato and alaninato ligands act as N,O-chelate ligands whereas in complexes 4 and 5 the amino acids act as N-donor ligands. The molecular structure of 1 (orthorhombic, Pbca, a=10.163(2), b=11.028(2), c=16.310(4) Angstrom, Z=8, R-1=0.0413, wR(2)=0.0953) exhibits a distorted octahedral coordinated Pt atom with a cis-PtCl2 unit and two N,O-coordinated glycinato ligands (OC-6-32). The complex is stabilized by intramolecular hydrogen bonds between the amino group and the C-O group as well as the chloro ligand. The crystal structure of 2 (orthorhombic, Pnma, a=23.262(9), b=11.149(4), c=15.834(5) Angstrom, Z=4, R-1=0.067, wR(2)=0.1644) shows a [PtCl4(gly)](-) unit and an [Na(18-cr-6)(H2O)(2)](+) unit linked via hydrogen bridges with a further crown ether molecule.

  DOI：

  10.1016/s0020-1693(96)05422-9