(trans-1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)superoxonickel(II) | 1195994-28-5

• 英文名称: (trans-1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)superoxonickel(II)
• 英文别名: [Ni(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O2)](1+)
• CAS: 1195994-28-5；916243-71-5
• 化学式: C₁₄H₃₂N₄NiO₂
• 分子量: 347.124
• InChiKey: ZVSGXHYGDXSTLG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双氧水 、 ((R,S,R,S)-1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(II) perchlorate 在 triethyl amine 作用下， 以 not given 为溶剂， 生成 (trans-1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)superoxonickel(II)
  参考文献：
  名称：

  Identification of an “End-on” Nickel−Superoxo Adduct, [Ni(tmc)(O₂)]⁺

  摘要：

  An "end-on" Ni2+-superoxo adduct has been prepared via two independent synthetic routes and its structure ascertained by spectroscopic and computational methods. The new structure type in nickel coordination chemistry is supported by resonance Raman and EPR spectroscopic features, the former displaying a high frequency nu (O-O) mode (1131 cm-1) consistent with significant superoxo character. The Ni2+-superoxo adduct oxidizes PPh3 to OPPh3 in quantitative yield.

  DOI：

  10.1021/ja0644879