[(η2-(4-trimethylsilyl-2-methyl-but-1-ene-3-yne))Cu(acetylacetonate)] | 866562-64-3

• 英文名称: [(η2-(4-trimethylsilyl-2-methyl-but-1-ene-3-yne))Cu(acetylacetonate)]
• 英文别名: [(eta.2-TMSMB)Cu(acac)]
• CAS: 866562-64-3
• 化学式: C₁₃H₂₁CuO₂Si
• 分子量: 300.94
• InChiKey: LVWBUJIFVKPQBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-甲基-4-三甲基硅基-1-丁烯-3-炔 以 乙醚 、 二氯甲烷 为溶剂， 生成 [(η2-(4-trimethylsilyl-2-methyl-but-1-ene-3-yne))Cu(acetylacetonate)]
  参考文献：
  名称：

  Me3SiCC–CMeCH2 copper(I) β-diketonates: Synthesis, solid state structure, and low-temperature chemical vapour deposition

  摘要：

  The ene-yne copper(I) beta-diketonates [(eta(2) -TMSMB)Cu(beta-diketonate)] (beta-diketonate = acetylacetonate/acac, 5; = 1,3-di-tertbutylacetonate/dbac, 6;=1,1,1,5,5,5-hexafluoroacetylacetonate/hfac, 7; TMSMB=4-TriMethylSilyl-2-Methyl-But-1-ene-3-yne, Me3SiC=C-CMe=CH2) are accessible by the reaction of [(eta(2) -TMSMB)Cu(mu-Cl)](2) (3) with [Na(beta-diketonate)] (beta-diketonate = acac, 4a; = dbac, 4b; = hfac, 4c) in a 1:2 molar ratio. Complexes 6 and 7 are also formed, when Cu2O (8) is reacted with H-hfac (9a) or H-dbac (9b), respectively.The solid state structure of 7 is reported. The copper(l) ion possesses a planar environment caused by the eta(2)-coordinated TMSMB ligand and the chelate-bound hfac group, while the CMe=CH2 entity stays free.The thermal properties of 5-7 were determined by applying ThermoGravimetry (TG) and Differential Scanning Calorimetry (DSC). All complexes decompose in a two-step process beginning at ca. 85 degrees C. Elimination of TMSMB produces [Cu(beta-diketonate)] which disproportionates to give [Cu(beta-diketonate)2] and elemental copper.Preliminary hot-wall Chemical Vapour Deposition experiments (CVD) were carried out with 7. Copper films were deposited onto TiN-coated oxidised silicon wafers at a precursor vaporisation temperature of 50 degrees C and a deposition temperature of 145 degrees C. The films were characterised by SEM and EDX. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.04.054