(2,2'-bibenzimidazole)dichlorobis(triphenylphosphine)rhenium(III) chloride | 705263-84-9

• 英文名称: (2,2'-bibenzimidazole)dichlorobis(triphenylphosphine)rhenium(III) chloride
• CAS: 705263-84-9
• 化学式: C₅₀H₄₀Cl₂N₄P₂Re*Cl
• 分子量: 1051.41
• InChiKey: CEBXGIHVSSLWMW-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-[ReOCl3(PPh3)2] 、 2-(1H-苯并咪唑-2-基)-1H-苯并咪唑 在 triphenylphosphine 作用下， 以 氯仿 为溶剂， 以77%的产率得到(2,2'-bibenzimidazole)dichlorobis(triphenylphosphine)rhenium(III) chloride
  参考文献：
  名称：

  Preparation and crystal structure of (2,2′-bibenzimidazole)dihalobis(triphenylphospine)rhenium(III) halides

  摘要：

  The reaction of ReOX3(PPh3)(2) (where X = Cl, Br) with 2,2'-bibenzimidazole (bibzimH(2)) in the presence of excess PPh3 yields the rhenium(III) cationic complexes [ReX2(PPh3)(2)(bibzimH(2))]X, in which the phosphines are trans to one another, whereas the plane perpendicular to this direction includes the chelating bidentate bibzimH(2) and two cis halogen ligands. The third halogen is a halide counter-ion. attached to the complex cation via a pair of N-(HX-)-X-... hydrogen bonds involving the two N-H groups of bibzimH(2). Crystallographic work on the chloro compound indicates that the departure from octahedral geometry is controlled by the bite of the bibzimH(2) ligand and that the presence of the phenylene groups does not introduce substantial steric hindrance. Despite the fact that the species is paramagnetic, the H-1 NMR spectra were fully assigned. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.01.012