| 370130-83-9

• CAS: 370130-83-9
• 化学式: C₃₄H₅₈Fe₂P₂
• 分子量: 640.476
• InChiKey: HCROUSLMTKRMHX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 甲苯 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Synthesis, Structure, and Reactivity of a Diphosphadiferratetrahedrane with a Fe−Fe Double Bond

  摘要：

  The short thermolysis of the butterfly molecule [{Cp'''(OC)2 Fe}2 P4 ] affords, besides [Cp'''FeP5 ] and [{Cp'''Fe}2 P4 ], the diphosphadiferratetrahedrane [{Cp'''Fe}2 (μ-CO)(μ-η2 :η2 -P2 )] with a Fe-Fe double bond in 18 % yield. The P2 building block was split photochemically into two μ-P ligands with elimination of CO. In the resulting dinuclear complex 1, the 31 P NMR signal is shifted to extremely low field (δ=1406.9), and the rhombic Fe2 P2 four-membered ring is almost orthogonal to the eclipsed Cp''' five-membered rings; Cp'''=tBu3 C5 H2 .

  DOI：

  10.1002/1521-3773(20010803)40:15<2859::aid-anie2859>3.0.co;2-k