| 168283-64-5

• CAS: 168283-64-5
• 化学式: C₁₂H₂₁FeOP
• 分子量: 268.119
• InChiKey: BEGYSSLLJWMBMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 氘代苯 为溶剂， 反应 0.08h， 以44%的产率得到C₃₉H₅₆CuFeN₂OP
  参考文献：
  名称：

  Mixed phosphine/carbonyl derivatives of heterobimetallic copper–iron and copper–tungsten catalysts

  摘要：

  Evolution of dihydrogen was observed from reactions of protic metal-hydride complexes FeCp(CO)(PR3) H and WCp*(CO)(2)(PR3)H with hydridic (NHC)CuH complexes, providing access to several heterobimetallic (NHC)Cu-FeCp(CO)(PR3) and (NHC)Cu-WCp*(CO)(2)(PR3) complexes that are the mixed phosphine/ carbonyl derivatives of previously studied catalysts for C-H borylation (NHC = N-heterocyclic carbene). The new complexes were characterized by multinuclear NMR spectroscopy, FT-IR spectroscopy, and in some cases X-ray crystallography. In one case, a (NHC)Cu(mu(2) -H)(2)FeCp(PPh3) complex was structurally characterized as the decomposition product of an unstable (NHC)Cu-FeCp(CO)(PPh3) derivative. Preliminary trials in C-H borylation catalysis are reported, including measurable activity under photochemical conditions. (C) 2018 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2018.09.062
• 作为产物：
  描述：

  iodocyclopentadienyl(triethylphosphine)carbonyliron(II) 、 lithium aluminium tetrahydride 在 水 作用下， 以 乙醚 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Scharrer, Eric; Chang, Seok; Brookhart, Maurice, Organometallics, 1995, vol. 14, # 12, p. 5686 - 5694

  摘要：

  DOI：

文献信息

• Insertion reactions of electrophilic iron carbene complexes with organosilanes: a synthetic and mechanistic study
  作者：Eric Scharrer、Maurice Brookhart

  DOI：10.1016/0022-328x(95)00117-9

  日期：1995.7

  Cationic iron carbene complexes of the type Cp(L)(CO)Fe = C(H)(R)+(L = PPh3, R = CH3, (L = PEt3, R = Ph3, CH3, CH2CH3, CH2CH2CH2CH3, CH2CH2CH2CH2CH2CH3) have been prepared and shown to react with organosilanes to give the products resulting from insertion of the carbene unit into the SiH bond. These reactions occur rapidly at low temperature, but yields are ca. 50% and a counterion-dependent by-product

  Cp（L）（CO）Fe = C（H）（R）+（L = PPh 3，R = CH 3，（L = PEt 3，R = Ph 3，CH 3，CH 2 CH 3，CH 2 CH 2 CH 2 CH 3，CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 3）已制备并显示出与有机硅烷反应生成由卡宾单元插入SiH键得到的产物。这些反应在低温下会迅速发生，但产率大约为1。50％，并形成抗衡离子的副产物。提出了一种与实验结果一致的机理。据报道，进行了可变温度NMR研究，从而可以独立观察机理途径中提出的几种中间体。