(C5Me4Et)Co(CO)As4S3 | 178674-40-3

• 英文名称: (C5Me4Et)Co(CO)As4S3
• CAS: 178674-40-3
• 化学式: C₁₂H₁₇As₄CoOS₃
• 分子量: 632.144
• InChiKey: YZJHIKCHNGQYFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 、 (C5Me4Et)2Co2(CO)2 以 xylene 为溶剂， 以25%的产率得到(C5Me4Et)CoAs6S
  参考文献：
  名称：

  Influence of Coordinated Cr(CO)₅ Groups on the Fragmentation of Realgar:  Synthesis and Characterization of the Novel Mixed Zintl Ion Complex (C₅Me₄Et)Co(η⁴-As₆S)

  摘要：

  A complex containing the novel mixed Zintl ion As6S2- is obtained from the reaction of (Cp2Co2)-Co-x(CO)(2) (Cp-x = C5Me4Et) with As4S4[Cr(CO)(5)](n) (n = 1, 2) in boiling xylene. (CpCoAs6S)-Co-x (1) is formed along with already known (Cp2CO2As6)-C-x (2), (CpCo)-Co-x(CO)As4S3 (3), and (Cp2Co2As2S3)-Co-x (4). The product distribution and nature of the products show that the Cr(CO)(5) groups play the role of sulfur-abstracting reagents rather than that of protective groups.

  DOI：

  10.1021/om970589j

文献信息

• The Reaction of As ₄ S _<i>n</i> ( <i>n</i> = 3, 4) and As ₂ S ₃ with (C ₅ Me ₄ R) ₂ Co ₂ (CO) ₂ (R = Me, Et): Fragmentation and Reassembling of Main‐Group Ligands by Organometallic Complexes
  作者：Henri Brunner、Heike Kauermann、Ludwig Poll、Bernhard Nuber、Joachim Wachter

  DOI：10.1002/cber.19961290611

  日期：1996.6

  The reaction of Cp2#Co2(CO)21 (Cp# = Cp* or Cpx; Cp* = C5Me5: a; Cpx = C5Me4Et: b) with equimolar amounts of As4Sn (n = 3, 4) and As2S3 was investigated at different temperatures. The formation of Cp2#Co2(CO)As2S23, Cp2#Co2As2S34, Cp3#Co3As2S45, and Cp3#Co3As4S26 was observed in ratios depending on the reaction conditions. Starting from As4S4 or As4S3 and 1b insertion of a CpxCo(CO) fragment into one

  CP 2 ＃ Co 2（CO）2 1（CP ＃ = CP *或CP x ; CP * = C 5 Me 5：a ; CP x = C 5 Me 4 Et：b）与等摩尔量的As 4的反应在不同温度下研究了S n（n = 3，4）和As 2 S 3。CP 2 ＃ Co 2（CO）As 2 S 2的形成3中，CP 2 ＃有限公司2作为2 s ^ 3 4中，CP 3 ＃共3作为2 s ^ 4 5和CP 3 ＃共3作为4 š 2 6在根据反应条件的比率进行了观察。从As 4 S 4或As 4 S 3和1b开始，以低收率将CP x Co（CO）片段插入笼子的As-As键之一中，从而导致CP xCo（CO）As 4 S 4 2b和CP x Co（CO）As 4 S 3 8。通过IR和1 H-NMR光谱以及X射线衍射分析研究了结构。CP 2 ＃ Co 2（CO）As 2 S 2 3可能被认为是整个反应过程