[{CuCl((2,6-iPr2C6H3)2acenaphthenequinonediimine)}2] | 1317668-23-7

• 英文名称: [{CuCl((2,6-iPr2C6H3)2acenaphthenequinonediimine)}2]
• 英文别名: [CuCl(1,2-bis(o,o'-bis(isopropyl)phenylimino)acenaphthene)]2
• CAS: 1317668-23-7
• 化学式: C₇₂H₈₀Cl₂Cu₂N₄
• 分子量: 1199.45
• InChiKey: VZEOJYHJDWJCBY-DQNYNXQBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(l) chloride 、 1,2-双-[(2,6-二异丙基苯基)亚氨基]苊 以 二氯甲烷 为溶剂， 以79%的产率得到[{CuCl((2,6-iPr2C6H3)2acenaphthenequinonediimine)}2]
  参考文献：
  名称：

  Synthesis, crystal structure and charge transfer spectra of dinuclear copper(I) complexes bearing 1,2-bis(arylimino)acenaphthene acceptor ligands

  摘要：

  A series of dinuclear halide bridged copper(I) complexes with a central [Cu(2)(mu-X)(2)] diamond core (X = Cl, Br and I) and substituted bis(imino)acenaphthene (BIAN) ligands acting as strong pi-acceptor subunits was prepared and characterized by elemental analysis, X-ray crystallography and various spectroscopic techniques. In the visible spectral range, the electronic spectra of these deeply colored air-stable compounds are dominated by low-lying charge transfer (CT) transitions. The corresponding broad absorption bands display a bathochromic shift and a decreasing amount of negative solvatochromism in the series X = Cl, Br and I. At the same time, the distance between the two metals becomes shorter and reaches the range of cuprophilic interactions. These systematic trends are interpreted as a decreasing amount of charge transfer character and a more pronounced delocalization between the two copper centers within in the same series. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.042

文献信息

• Cationic and Neutral (Ar‐BIAN)Copper(I) Complexes Containing Phosphane and Arsane Ancillary Ligands: Synthesis, Molecular Structure and Catalytic Behaviour in Cycloaddition Reactions of Azides and Alkynes
  作者：Lidong Li、Patrícia S. Lopes、Cláudia A. Figueira、Clara S. B. Gomes、M. Teresa Duarte、Vitor Rosa、Christophe Fliedel、Teresa Avilés、Pedro T. Gomes

  DOI：10.1002/ejic.201201211

  日期：2013.3.12

  Invited for the cover of this issue are the groups of Pedro T. Gomes (Universidade Tecnica de Lisboa) and Teresa Aviles (Universidade Nova de Lisboa). The cover image shows the structure of one of the catalysts against a background of a bridge symbolising the collaboration between the two groups.

  Pedro T. Gomes (Universidade Tecnica de Lisboa) 和 Teresa Aviles (Universidade Nova de Lisboa) 受邀登上本期封面。封面图片展示了其中一个催化剂的结构，背景是一座象征两个团体之间合作的桥梁。
• Copper(<scp>ii</scp>) complexes of bis(aryl-imino)acenaphthene ligands: synthesis, structure, DFT studies and evaluation in reverse ATRP of styrene
  作者：Christophe Fliedel、Vitor Rosa、Carla I. M. Santos、Pablo J. Gonzalez、Rui M. Almeida、Clara S. B. Gomes、Pedro T. Gomes、M. Amélia N. D. A. Lemos、Gabriel Aullón、Richard Welter、Teresa Avilés

  DOI：10.1039/c4dt01069h

  日期：——

  the coordination sphere of the Cu(II) centre. In the case of the complex 1, an intermediate coordination geometry around the Cu(II) centre, between square planar and tetrahedral, was revealed, while the complex 2 showed an almost square planar geometry. The structural differences and evaluation of energetic changes were rationalised by DFT calculations. Analysis of the electrochemical behaviour of complexes

  配方[CuCl 2（Mes-BIAN）]（1）的两个新的Ar-BIAN Cu（II）配合物（其中Ar-BIAN =双（芳基-亚氨基）ac ）（Mes = 2,4,6-Me 3 C通过悬浮在二氯甲烷中的CuCl 2与相应的配体Mes- BIAN （6 H 2）和[CuCl 2（Dipp-BIAN）]（2）（Dipp = 2,6-iPr 2 C 6 H 3）合成。在氩气气氛下溶解在二氯甲烷中的L1）和Dipp-BIAN（L2）。试图通过溶解CuCl 2来获得这些化合物在甲醇中，在有氧条件下，加入相应配体的二氯甲烷溶液，也得到化合物1，但在L2的情况下，改为获得Cu（I）二聚体[CuCl（Dipp-BIAN）] 2（3）化合物2。通过元素分析，MALDI-TOF质谱，FT-IR，1 H NMR和EPR光谱技术对化合物进行了全面表征。化合物1-3的固态分子结构通过单晶X射线衍射测定，显示出预期的A