Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)Cl | 217812-84-5

• 英文名称: Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)Cl
• 英文别名: (octaethylporphyrinato dianion)Ru(NO)Cl；(octaethylporphyrinato)Ru(NO)Cl；(OEP)Ru(NO)Cl
• CAS: 217812-84-5
• 化学式: C₃₆H₄₄ClN₅ORu
• 分子量: 699.301
• InChiKey: OCIUGUIMXRRFNL-SBYLDBAISA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)Cl 以 二氯甲烷 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)RuNOsO3
  参考文献：
  名称：

  Heterobimetallic nitrido-bridged Ru(II)NOs(VIII) and Ru(II)NOs(VI) complexes containing ruthenium porphyrins

  摘要：

  Treatment of Ru(por)(NO)(OTf) (por=dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin H-2(OEP) or 5,10,15,20-tetra(p-tolyl)porphyrin H-2(TTP), OTf=triflate) with [(NBu4)-Bu-n][OsO3N] afforded the nitrido-bridged Ru(II)-Os(VIII) complexes [(por)(NO)RuNOsO3] (por=OEP (3) or TTP (4)). The structure of 3 has been established by X-ray crystallography. The Ru-N(O), Ru-N(Os and Os-N distances in 3 are 1.83(2, 2.03(1) and 1.79(1) Angstrom, respectively; the Ru-N-O and Ru-N-Os angles are 153(1) and 138.4(8)degrees, respectively. Reaction of Ru(por)(NO)(OTf) with [(NBu4)-Bu-n]OsNL2] (H2L = 3,4-toluenedithiol) gave the nitrido-bridged Ru(II)-Os(VI) complexes (por)(NO)RuNOsL2 (por = OEP (5), TTP (6)). Treatment of Ru(OEP)(NO)(OTf) with ReN(Et(2)dtc)(2) (Et(2)dtc = N,N-diethyldithiocarbamate) afforded the Ru(IT)-Re(V) complex (OEP)(NO)RuNRe(Et(2)dtc)(2)(OTf) (7). Complexes 3 and 4 exhibit porphyrin-centered oxidation along with Os(VIII)-Os(VIT) and Ru(II)-Ru(I) reductions. Complexes 5 and 6 exhibit Os(VII)-Os(VI) and porphyrin ring oxidation along with Ru(II)-Ru(I) reduction. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00096-1
• 作为产物：
  描述：

  Ru(octaethylporphyrinate)(NO)(ONO) 在 air 作用下， 以 二氯甲烷 为溶剂， 生成 Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(NO)Cl
  参考文献：
  名称：

  Miranda, Katrina M.; Bu, Xianhui; Lorkovic, Ivan, Inorganic Chemistry, 1997, vol. 36, # 21, p. 4838 - 4848

  摘要：

  DOI：

文献信息

• Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)
  作者：Nan Xu、Jonghyuk Lee、Douglas R. Powell、George B. Richter-Addo

  DOI：10.1016/j.ica.2004.06.031

  日期：2005.6

  A new high-yield preparative route to (por)Ru(NO)Cl compounds (por=porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the Ru-N-O linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered. (c) 2004 Elsevier B.V. All rights reserved.
• Cyclic voltammetric and fiber-optic infrared spectroelectrochemical studies of six-coordinate (por)Ru(NO)Cl compounds (por=porphyrinato dianion)
  作者：Mona A. El-Attar、Nan Xu、Dennis Awasabisah、Douglas R. Powell、George B. Richter-Addo

  DOI：10.1016/j.poly.2012.03.034

  日期：2012.6

  The redox behavior of representative (por)Ru(NO)Cl complexes (por = OEP, T(p-OMe)PP, T(p-CF3)PP) have been obtained. The compounds possess linear RuNO moieties as exemplified by the X-ray crystal structure of (T(p-OMe)PP)Ru(NO)Cl (Ru-N-O = 174(2)degrees, Ru-N(O) = 1.790(17) angstrom, Ru-Cl = 2.220(6) angstrom). The first electrooxidations of the (por)Ru(NO)Cl compounds in CH2Cl2 occur in the order OEP (+0.51 V) < T(p-OMe)PP (+0.57 V) < T(p-CF3)PP (+0.84 V) (versus Fc/Fc(+)). We have utilized infrared reflectance spectroelectrochemistry to determine that the first oxidations are porphyrin centered. In addition, the reductions are largely RuNO centered. (C) 2012 Elsevier Ltd. All rights reserved.