[Bu4N][Ir4(CO)10(SnPh3)2(μ-H)] | 1265788-28-0

• 英文名称: [Bu4N][Ir4(CO)10(SnPh3)2(μ-H)]
• CAS: 1265788-28-0
• 化学式: C₁₆H₃₆N*C₄₆H₃₁Ir₄O₁₀Sn₂
• 分子量: 1992.51
• InChiKey: BQMWZQDZEYHMBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetra-n-butylammonium hydroxide 、 [Bu4N][Ir4(CO)11(SnPh3)] 、 三苯基氢氧化锡 以 甲醇 为溶剂， 以18%的产率得到[Bu4N][Ir4(CO)10(SnPh3)2(μ-H)]
  参考文献：
  名称：

  A New Method for Introducing Tin Ligands into Tetrairidium Dodecacarbonyl

  摘要：

  The reaction of Ph3SnOH with Ir-4(CO)(12) in the presence of[Bu4N]OH in methanol solvent gave two products, [Bu4N][Ir-4(CO)(11)(StiPh(3))] (I; 45% yield) and [Bu4N][Ir-4(CO)(10)(SnPh3)(2)(mu-H)] (2; 5.5% yield), and the reaction of Ir-4(CO)(11)(PPh3) with Ph3SnOH in the presence of[Bu4N]OH gave the complex Ir-4(CO)(10)(SnPh3)(PPh3)(mu-H) (3) in 44% yield. It is proposed that the reactions occur by the addition of the anion [OSnPh3](-) generated in situ to a CO ligand of the Ir-4(CO)(12) to form a stannyl-substituted metallocarboxylate ligand that subsequently loses CO2 and transfers the SnPh3 group to a metal atom.

  DOI：

  10.1021/om1012083