[Fe(III)(5-NO2sal2trien)]PF6 | 74111-30-1

• 英文名称: [Fe(III)(5-NO2sal2trien)]PF6
• CAS: 74111-30-1
• 化学式: C₂₀H₂₂FeN₆O₆*F₆P
• 分子量: 643.242
• InChiKey: PDQREIXAHCDLOB-WKVAKUHSSA-L

反应信息

• 作为反应物：
  描述：

  manganese(II) chloride tetrahydrate 、 硝基甲烷 、 silver tris(oxalato)chromate(III) 、 [Fe(III)(5-NO2sal2trien)]PF6 以 甲醇 、 硝基甲烷 为溶剂， 生成 [Fe(III)(5-NO2sal2trien)][Mn(II)Cr(III)(ox)3]*MeNO2*0.5H2O
  参考文献：
  名称：

  2D and 3D bimetallic oxalate-based ferromagnets prepared by insertion of different FeIII spin crossover complexes

  摘要：

  The syntheses, structures and magnetic properties of the compounds of formula [FeIII(5-NO2sal2-trien)][MnIICrIII(ox)3]·CH3NO2·0.5H2O (1) and [FeIII(5-CH3Osal2-trien)][MnIICrIII(ox)3] (2) are reported. The structure of 1, that crystallizes in the P21 chiral space group, presents a 2D honeycomb anionic layer formed by MnII and CrIII ions linked through oxalate ligands and a cationic layer of [FeIII(5-NO2sal2-trien)]+ complexes intercalated between the 2D oxalate network. The structure of 2, that crystallizes in the Pna21 acentric space group, presents a 3D achiral anionic network formed by MnII and CrIII ions linked through oxalate ligands with [Fe(5-CH3Osal2-trien)]+ complexes intercalated within the 3D oxalate network. The magnetic properties of 1 and 2 indicate that both compounds undergo a long-range ferromagnetic ordering at ca. 5 K. On the other hand, the inserted FeIII cations remain mainly in the low-spin (LS) state in the case of 1 and in the high-spin (HS) state in the case of 2.

  DOI：

  10.1039/c001067g