Au2Cl2((3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine)2 | 1313494-94-8

• 英文名称: Au2Cl2((3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine)2
• CAS: 1313494-94-8
• 化学式: C₃₈H₄₂Au₂Cl₂N₄P₂
• 分子量: 1081.56
• InChiKey: FFXJOJUITUPLLR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (Cl)(tetrahydrofuran)gold(I) 、 1,-[2-(diphenylphosphanyl)ethyl]-3,5-dimethylpyrazole 以 二氯甲烷 为溶剂， 以90%的产率得到Au2Cl2((3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine)2
  参考文献：
  名称：

  Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I) and Au(I) precursors

  摘要：

  The reactivity of (3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenylphosphine (L) hybrid ligand against Cu(I), Ag(I) and Au(I) has been assayed and compounds [Cu(L)(2)](PF6) (1), [Ag(L)](2)(PF6)(2)center dot 2C(2)H(4)Cl(2)center dot 2C(4)H(10)O (2) and [AuCl(L)](2) (3) have been isolated and fully characterised. A fully characterisation by analytical and spectroscopic methods of 1-3 are presented and X-ray crystal structures of 1 and 2 are also reported. The similar data obtained between 2 and 3 permits to do a serious purpose of the structure of 3 in solid and solution. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.04.019