Co3(azide)2(benzenecarboxylate)4(1,10-phenanthroline)2 | 1338596-96-5

• 英文名称: Co3(azide)2(benzenecarboxylate)4(1,10-phenanthroline)2
• CAS: 1338596-96-5
• 化学式: C₅₂H₃₆Co₃N₁₀O₈
• 分子量: 1105.9
• InChiKey: WXVODMRLMUNQQM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯甲酸 、 cobalt(II) chloride hexahydrate 、 1,10-菲罗啉 、 sodium azide 以 水 为溶剂， 以67%的产率得到Co3(azide)2(benzenecarboxylate)4(1,10-phenanthroline)2
  参考文献：
  名称：

  A unique mixed-bridged trinuclear Co (II) complex and its extended system: Structural and magnetic studies

  摘要：

  Two novel complexes, [Co-3(N-3)(2)(bca)(4)(phen)(2)] (1, bca = benzenecarboxylic acid, phen = 1,10-Phenanthroline) and [Co-3(N-3)(2)(bdc)(2)(Phen)(2)](n) (2, bdc = terephthalic acid), have been synthesized hydrothermally and characterized by single crystal X-ray diffraction (XRD), infrared spectra (IR) and element analysis (EA). Complex 1 features unprecedented discrete linear Co-3 clusters that formed by mixed (mu-EO-N-3)(mu-COO)(2) (EO = end-on) triple bridges whereas 2 presents an extended (2D) network based on the similar trinuclear units as 1. Magnetic studies of 1 and 2 reveal that the mixed (mu-EO-N-3)(mu-COO)(2) triple bridges transmit ferromagnetic behavior. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.08.014