Rh(COD)(4,5-diazafluorene(1-)) | 1040254-99-6

• 英文名称: Rh(COD)(4,5-diazafluorene(1-))
• CAS: 1040254-99-6
• 化学式: C₁₉H₁₉N₂Rh
• 分子量: 378.279
• InChiKey: RANYENVXPRVCNX-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 4,5-二氮杂芴 生成 Rh(COD)(4,5-diazafluorene(1-))
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
  作者：Huiling Jiang、Datong Song

  DOI：10.1021/om800312d

  日期：2008.7.1

  The reaction of 4,5-diazafluorene (LH) and NaH generates NaL, which reacts with Pd(PPh3)(2)Cl-2 and [Rh(COD)Cl](2) to afford [Pd(PPh3)ClL](2) (1) and Rh(COD)L (2), respectively. Both 1 and 2 were fully characterized by NMR, elemental, and single-crystal X-ray diffraction analyses. Compound 2 can promote the hydrogenation of a variety of terminal olefins, without affecting the carbonyl groups in the substrates. Attempts to crystallize NaL results in the formation of a partially protonated species, Na-2(LH)(2)L-2, whose structure is confirmed by X-ray crystallography.