Synthesis, reactivity, and electrochemical behaviour of new five-co-ordinate nitrosyl cobalt complexes
作者:Gabriele Albertin、Emilio Bordignon、Gian Antonio Mazzocchin、Angelo A. Orio、Renato Seeber
DOI:10.1039/dt9810002127
日期:——
The synthesis and characterization of some newfive-co-ordinate mononitrosyl cobaltcomplexes of the type [CoL4(NO)][BPh4]2[L = P(OMe)3, P(OEt)3, or PPh(OEt)2] is described. The reactivity of these compounds with π-acceptor ligands such as NO, CO, phosphite, and isocyanide is discussed. Furthermore, the reaction with molecular oxygen and with halide ions (X–) has been investigated and a new method