[RuCp(η1(P)-PPh2CH=C(CH2)3-η3(C,C,N)-CCHNEt2)](1+) | 868611-07-8

• 英文名称: [RuCp(η1(P)-PPh2CH=C(CH2)3-η3(C,C,N)-CCHNEt2)](1+)
• CAS: 868611-07-8
• 化学式: C₂₈H₃₃NPRu
• 分子量: 515.62
• InChiKey: NEKPYBKFRHMVIZ-KSTMOPHVSA-N

反应信息

• 作为产物：
  描述：

  [Ru(C5H5)[η1-(P)-(C6H5)2PCHC(CH2)3-η3-(C,C,N)-CCHN(C2H5)2]][PF6] 以 not given 为溶剂， 以85%的产率得到[RuCp(η1(P)-PPh2CH=C(CH2)3-η3(C,C,N)-CCHNEt2)](1+)
  参考文献：
  名称：

  Ruthenium-Mediated Insertion of an Unsaturated C4 Unit into the P−N Bond of an Aminophosphine Ligand

  摘要：

  The reactions of 1,6-heptadiyne and 1,7-octadiyne with [RuCp(PPh2NEt2)(CH3CN)(2)](+) afford the eta(3)-phosphaallyl-eta(2)-vinylamine complexes [RuCp(eta(3)-(P, C, C)-PPh2CH=C(CH2)(n)-eta(2)(C, C)-C=CHNEt2)](+) (n=3, 4), which cleanly rearrange to give the eta(1)-phosphaallyl-eta(3)- azaallyl complexes [RuCp(eta(1)(P)-PPh2CH=C(CH2)(n)-eta(3)-(C,C,N)-CCHNEt2)](+) (n=3, 4).

  DOI：

  10.1021/om050688u