[Rh(1,5-cyclooctadiene)(CH3C11H9N2(C5H4N)2)]BPh4 | 1073316-49-0

• 英文名称: [Rh(1,5-cyclooctadiene)(CH3C11H9N2(C5H4N)2)]BPh4
• 英文别名: [Rh(cod)(CH3C11H9N2(C5H4N)2)]BPh4
• CAS: 1073316-49-0
• 化学式: C₂₄H₂₀B*C₃₀H₃₂N₄Rh
• 分子量: 870.75
• InChiKey: VCOCPYYSBVRNTI-KEUNEWJHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Rh(1,5-cyclooctadiene)(CH3C11H9N2(C5H4N)2)]Cl 、 四苯硼钠 以 二氯甲烷 为溶剂， 以90%的产率得到[Rh(1,5-cyclooctadiene)(CH3C11H9N2(C5H4N)2)]BPh4
  参考文献：
  名称：

  Hydrogen-bonding network in new scorpionate-type ligand composed of pyridine/pyrrole hybrid and anion-binding behavior of the corresponding rhodium complexes in alkyne cyclotrimerization reaction

  摘要：

  New heteroscorpionate ligands (1 and 2) having a di(pyridin-2-yl)(1H-pyrrol-2-yl) methane substructure are synthesized. X-ray crystallographic analysis on 1 and 2 reveals that they form unique hydrogen bonding networks depending on the size of neighboring groups in solid states. 1 and 2 can form cationic rhodium( I) complexes, wherein the counter anions form hydrogen bondings with the pyrrolic NH moiety. In alkyne cyclotrimerization reactions using those complexes as catalyst, the catalytic activity is significantly enhanced when electron-donating counter anions is placed near the metal center. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.07.005