[Ru(F)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(N2)](PF6) | 1246457-59-9

• 英文名称: [Ru(F)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(N2)](PF6)
• CAS: 1246457-59-9
• 化学式: C₁₄H₃₂FN₆Ru*F₆P
• 分子量: 549.481
• InChiKey: RDSYBVKTIXZQIH-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  氟硼酸钠 、 [Ru(F)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(N2)](PF6) 生成 [Ru(F)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(N2)](BF4)*H2O
  参考文献：
  名称：

  A pH-stable Ruthenium(II)-based Sensing System for Dissolved Dinitrogen

  摘要：

  Building on a previous design for a Ru-based dissolved N2 sensor, we report an adaptation that allows for reversible data storage. The N2 complex can be “fixed” and made stable across a range of pHs by the substitution of OH− with F− to form [RuII(F)(TMC)(N2)]+ (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane). The addition of Ca2+ and irradiation with light at high pH removes the F−, thereby regenerating the sensor in its reversible configuration.

  DOI：

  10.1246/cl.2010.128