π-CH3C5H4Mn(CO)2(SONH) | 315669-19-3

• 英文名称: π-CH3C5H4Mn(CO)2(SONH)
• CAS: 315669-19-3
• 化学式: C₈H₈MnNO₃S
• 分子量: 253.16
• InChiKey: CJEQWZUJMHENEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 π-CH3C5H4Mn(CO)2[S(O)NSiMe3] 生成 π-CH3C5H4Mn(CO)2(SONH)
  参考文献：
  名称：

  Koordination und Reaktivität von Sulfinylimiden RNSO in Cyclopentadienyldicarbonylmangan-Komplexen

  摘要：

  The coordination behaviour of sulfinylimides RNSO (R = SiMe3, Ph) towards CpMn(CO)(3) (Cp = C5H5, C5H4CH3) has been studied. Under total exclusion of water the substitution products CpMn(CO)(2){S(O)NR} (2a,b, 2a',b) with mu (1)-S-linkage are formed. In the presence of water, however, the SO2 complexes 3, 3' as iminofree hydrolysis products are obtained. There are only spectroscopic indications for the directed hydrolytic conversion of the silyl derivatives 2a, 2a' into the unstable HNSO complexes 4, 4' by cleavage of the Si-N-bond and retention of the cumulene moiety. The molecular structures of -piC5H5Mn(CO)(2)-{S(O)NSiMe3} (2a) and pi -C5H4CH3Mn(CO)(2) (3') were elucidated by single crystal X-ray analyses.

  DOI：

  10.1002/1521-3749(200011)626:11<2313::aid-zaac2313>3.0.co;2-p